Hi iKoffeeholic,
Welcome to the PayPal Community Forums!
That's a good question. In this case it will depend on the policies of the card issuer. Likely the card issuer will decline the payment since the amount would be more than the available balance on the card.
I recommend contacting Walmart for more information regarding their policies. If it's anything like my previous experiences with gift cards you will probably have to request a paper check be issued for the remaining balance since it's so low.
- Dustin
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