Website Payments Standard Subscriptions start on the day they're subscribed to. You cannot specify a fixed day for them to start on (unless you use a workaround; see my link later on in this post).
Recurring payments can have a specific start date. The entry recurring payments product is Express Checkout Recurring Payments.
Note however that Express Checkout does not work off the general 'button' concept and you'll need a seasoned developer to integrate it into your website.
See also my answer in https://www.paypal-community.com/t5/Merchant-services/Creating-a-redirect-to-Paypal/m-p/325416 which also describes this feature.
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