I just fended off a similar attempt.
When he offered more than I was asking and said he'd send his own shipper, it was fairly evident that it was a scam.
The funny part is that the following three emails (with the Western Union part) ignored my message to quit and assumed I was going along. It's clear that it's running some kind of automation untouched by human brains.
I sent the raw email files to spoof@paypal.com.
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