I had the same problem but with a call to Paypal and some research I did on my own here is the page you need to go to: https://www.paypal.com/us/cgi-bin/webscr?cmd=_profile-logins-change-admin (You may need to log into your PP account). Click on the drop down list of email address (or add a new one) and then click onto continue. Note: if you are trying to change your administrative address to an address that is currently your primary address, you will have to change your primary email address first.
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