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Things have changed in some countries since this thread was started and you may be able to do this....
Click on the profile tab (icon next to log out) > Click on payments third option along on the thick blue band top of page > second down click on update next to your prefered way to pay and put a dot in one of the options listed.
However just to mention that you are only allowed x2 paypal accounts if x1 is personal and the other x1 is business, if you have x2 of the same type then you risk them being limited.