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I send money on accident as goods and services when it was supposed to be for a family member under friends and family and now the person can't access it until there's an invoice or 21 days is up and I need to know how to get this release to them right away because it's for bills and very important
Unlikely you can do anything about it now you have sent it.
You could try getting the receiver to mark the transaction as SHIPPED and then that 'may' give you the option to confirm receipt on your paypal account, the confirm receipt button is not always there but if it is then the funds may be released a bit quicker.
Advice is voluntary. Kudos / Solution appreciated.