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You can't link and pay via a bank account in your country, only via a linked and confirmed card.
Welcome to the Community and thank you for your post!
Sorry to hear you are experiencing issues with a payment. Did you try using a different card?
If you would like to call in, you can find the correct phone number for your country by clicking 'Help & Contact' at the bottom of the PayPal homepage and by clicking 'Contact us' and then 'Call us'. You can also contact us on Facebook or on Twitter.
Hope this helps,