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There is no paypal buyer protection for a motor vehicle on paypal so be very careful.
Personally i would take cash on collection WHEN you have viewed the car and are happy with it.
Depends if they are new sellers and subject to the new seller hold.
Or depends if paypal put a security review on it as its a large sum of money.
fee is published on Paypal site.
You may have to call Paypal in advance to seek permission to send such a large sum of money.
you can carry a bank cashier check,if you are travelling within USA,and your bank has branches in the city where you are going,you two can meet in branch parking lot and afterwards go inside the bank to transact the deal.