Hello @Joehamilton2011, that's a great question! As long as Walmart's Money Center or Customer Service desk is open, you should be able to. Here's a link to one of our Help Center articles I think may help out: https://www.paypal.com/us/smarthelp/article/what-is-%22get-cash%22-and-how-do-i-use-it-faq3970 .
Thank you for reaching out on our Community Help Forum and have a great day!
- Jon
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