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I've just added my Barclays business account to paypal but I'm being told it is only available for withdrawl.
Any idea how to enable it to make payments also?
Welcome to the community forum and thanks for posting.
If your bank is only available for withdrawal it would mean that it has not been confirmed yet. You will find the steps to confirm it here https://www.paypal.com/gb/selfhelp/article/FAQ686 . When you added the bank we would send a direct debit agreement to your bank along with the code you need to confirm it.
If that direct debit was not accepted I would recommend removing the bank and adding it again to resend it.
I hope this helps.